When Ammonia Ruled the World - Short #270

In this short podcast episode, Bryan takes us on a history journey back to when ammonia ruled the world.

In the mid-1800s, before R-12, many inventors and scientists experimented with vapor-compression refrigeration systems to make ice. They used a variety of refrigerants in their patents, including ether, ethyl ether, carbon dioxide, sulfur dioxide, methyl chloride, and ammonia. Each one had tradeoffs, but ammonia was the favorite because it was inexpensive, very good at moving heat, and useful because its odor made leaks obvious (although it was toxic and irritated the lungs and mucus membranes).

Toxic refrigerants, particularly sulfur dioxide and methyl chloride, were common refrigerants but had plenty of negative press due to the many deaths they caused. In response to the public's reservations about toxic refrigerants, Thomas Midgley from General Motors (who developed leaded gasoline) teamed up with Charles Kettering and DuPont to find a refrigerant that was non-toxic, non-flammable, and non-corrosive. In 1930, they announced dichlorodifluoromethane, also known as R-12 (a CFC) and trademarked as Freon. This refrigerant was non-toxic, non-flammable, and had no odor, and it effectively replaced the methyl chloride, sulfur dioxide, and ammonia.

However, many decades later, scientists discovered that chlorine-bearing compounds were destroying the ozone layer. To combat the environmental damage, many nations signed the Montreal Protocol in the 1980s, which would effectively phase out R-12, R-11, and other CFC refrigerants. Over time, the regulations have tightened on HCFCs and high-GWP HFCs, leading us to where we are now with lower-GWP A2L HFCs and HFO blends. As with the old refrigerants, each refrigerant had a tradeoff.

Meanwhile, this whole time, ammonia never became truly obsolete and quietly remained the lifeblood of industrial refrigeration, and it also had no global warming potential OR ozone-depletion potential. Ammonia systems run with relatively little charge, especially when paired with CO2, and ammonia is still a powerhouse today because of its chemical formula (NH3), good compression ratio, and excellent latent heat of vaporization.

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