After a charming 911 operator mysteriously loses 2 husbands to the same so-called "natural causes" within only a few years, friends and family of the victims come together to make sure she never strikes again.

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References:

Black Widow - Marion Collins

Charmed to Death (Oxygen) S1E6 - Dispatched

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Credits: Love Murder is hosted by Jessie Pray and Andie Cassette, produced by Nathaniel Whittemore and edited by Kyle Barbour-Hoffman

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That Girl is Poison: Lynn Turner, Glenn Turner and Randy Thompson