Psilocybin contains mushrooms growing in the dung of cattle many dung growing so-called coprophitic coprolitic mushrooms produce psilocybin among them stropharicubensis. Our early ancestors also tested other kinds of food they were digging for corms with pointed sticks and I'm sure there were many ecological and medical disasters as a consequence of this. We're looking for some kind of factor which could have exploded the human brain size at a rate ten times faster than evolution normally takes place it's going to be an unusual situation perhaps the need to throw a boulder a distance accurately or perhaps contact with an unusual food item or drug containing plant but it was something unusual

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