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The Cherenkov Effect
The problem with Ray's experiment was that it was only sensitive to neutrinos that were emitted by a small side branch of the sun's output. So there were two issues that were addressed by the next generation experiments. One was that this idea of producing a few atoms of radioactive argon, flushing them out of the tank and counting them doesn't actually prove to be detecting neutrinos from the sun at all. And you don't even know exactly when those argon atoms were produced. If you were a real skeptic, you could claim that in fact Ray Davies had detected no solar neutrinos, he was detecting some form of background that we hadn't thought of.