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The Trial and Error of a Death Victim
Toxicology is very much in its infancy and this is done by a process of elimination. The search for poison in a bottle was quite a laborious process. John Tall had to have known that it would have been an excruciating death. Poisoners have control over how painful their victim's deaths could be. So when you're picking that poison, you're picking it partly in a vindictive way.